CNBC will premiere an all-new The Entrepreneurs, hosted by Donny Deutsch this Thursday (April 2, 2009) at 9P ET and 10P PT. Celebrity chef Rick Bayless discusses how a love for Mexican food and a brilliant business plan helped create Frontera Foods‘ multi-million dollar empire. Also see how Toms Shoes became profitable giving away a pair for every shoe sold? Blake Mycoskies explains the motivation behind his company and how it helps children around the world.